炭材料科學與工程：從基礎到應用

1 Introduction
1.1 Carbon Materials
1.2 Short History of Carbon Materials
References
1.3 Classic Carbons, New Carbons and Nanocarbons
1.3.1 Classic carbons
1.3.2 New carbons
1.3.3 Nanocarbons
References16
1.4 Construction and Purposes of the Present Book
2 Fundamentals of Carbon Materials
2.1 Carbon Families
2.1.1 Carboncarbon bonds
2.1.2 Carbon families
2.1.3 Relations to neighboring atoms
2.2 Structure and Texture of Carbon Materials
2.2.1 Structure
2.2.2 Structural development with heat treatment (Carbonization and graphitization)
2.2.3 Nanotexture
2.2.4 Microtexture (Agglomeration)
References
2.3 Nanotexture Development in Carbon Materials (Carbonization)
2.3.1 Formation processes of carbon materials
2.3.2 Gas phase carbonization
2.3.3 Solid phase carbonization
2.3.4 Liquid phase carbonization
References
2.4 Novel Techniques for Carbonization
2.4.1 Template method
2.4.2 Polymer blend method
2.4.3 Pressure carbonization
2.4.4 High yield carbonization
2.4.5 Low temperature carbonization
References
2.5 Structural Development in Carbon Materials (Graphitization)
2.5.1 Structure parameters
2.5.2 Graphitization behavior
2.5.3 Carbon materials with planar orientation
2.5.4 Carbon materials with axial orientation
2.5.5 Carbon materials with point orientation
2.5.6 Carbon materials with random orientation
2.5.7 Relations among structure parameters
2.5.8 Graphitization process
2.5.9 Graphitizing and nongraphitizing carbons
2.5.10 Heterogeneous graphitization (Multiphase graphitization)
References
2.6 Acceleration of Graphitization
2.6.1 Catalytic graphitization
2.6.2 Stress graphitization
2.6.3 Graphitization of exfoliated carbon fibers
References
2.7 Pore Development in Carbon Materials
2.7.1 Pores in carbon materials
2.7.2 Identification of pores in carbon materials
2.7.3 Pore development in carbon materials
References
2.8 Introduction of Foreign Species
2.8.1 Possibility to introduce foreign species into carbon materials 226
2.8.2 Intercalation
2.8.3 Substitution
2.8.4 Doping
2.8.5 Dispersion of fine metal particles
References
3 Engineering and Applications of Carbon Materials
3.1 Polycrystalline Graphite Blocks
3.1.1 Production
3.1.2 Applications
3.1.3 Filler cokes and binder pitches
3.1.4 Properties
References
3.2 Highlyoriented Graphite
3.2.1 Highlyoriented graphite
3.2.2 Kish graphite 308
3.2.3 Highlyoriented pyrolytic graphite (HOPG)
3.2.4 Graphite films derived from polyimide films
3.2.5 Flexible graphite sheets
References
3.3 Non-graphitizing and Glass-like Carbons
3.3.1 Structural characteristics
3.3.2 Properties
3.3.3 Glass-like carbons
References
3.4 Fibrous Carbons
3.4.1 Classification of fibrous carbons
3.4.2 Carbon fibers
3.4.3 Carbon nanotubes and nanofibers
3.4.4 Single wall carbon nanohorns
3.4.5 Carbon microcoils
References
3.5 Porous Carbons
3.5.1 Activated carbons
3.5.2 Novel techniques to control pore structure
3.5.3 Exfoliated graphite
References
3.6 Carbonbased Composites
3.6.1 Carbonbased composites
3.6.2 Carbon/carbon composites (C/Cs)
3.6.3 Carbon fiber reinforced plastics
3.6.4 Carbon/ceramics composites
3.6.5 Carbon/metal composites
References
3.7 Intercalation Compounds
3.7.1 Possible applications
3.7.2 High conductivity function
3.7.3 Electrochemical functions
3.7.4 Catalytic functions
3.7.5 Gas adsorption and storage
3.7.6 Other functions
References
3.8 Carbon Materials for Energy Storage
3.8.1 Rechargeable batteries
3.8.2 Electrochemical capacitors
3.8.3 Storage of hydrogen gas
3.8.4 Storage of methane gas
3.8.5 Applications to other batteries
References
3.9 Carbon Materials for Environment Remediation
3.9.1 Carbon/anatase composites
3.9.2 Carbon materials for sorption of viscous fluids
3.9.3 Carbon fibers
References
Acknowledgements
Subject Indexes